| ORGN | Tuesday, August 18, 2009 | ||
1:00 PM-5:00 PM Walter E. Washington Convention Center -- 204A/B, Oral | |||
Metal-Mediated Reactions and Syntheses | |||
| Sponsored by: | ORGN | ||
| Presiding: | Kalman J. Szabo | ||
| 1:00 PM | 397 | Selective catalytic hydrogenation of 1-nitro-cyclohexene to cyclohexanone oxime in a high pressure continuous flow system Eszter Varga, Attila Wootsch, Tamás Nagy, Ildikó Kovács, István Mándity, László Ürge, Ferenc Darvas, Richard Jones | |
| 1:20 PM | 398 | Developing a fluorometric detection method for mercury and palladium based on classic metal-catalyzed reactions Fengling Song, Shin Ando, Kazunori Koide | |
| 1:40 PM | 399 | Pd N-heterocyclic carbene catalysts: How much bigger is better? Michael G. Organ, Selçuk Çalimsiz, Mahmoud Sayah, Ka Hou Hoi, Niloufar Hadei, Gregory A. Chass | |
| 2:00 PM | 400 | The role of bulkiness in promoting Pd-NHC-catalyzed cross-couplings: A synergy between experiment, spectroscopy, and theory Gregory A. Chass, Florian Kargl, De-Cai Fang, Michael G. Organ | |
| 2:20 PM | 401 | Palladium catalyzed allylic oxidations of terminal alkenes William H. Henderson, Christopher T. Check, Nicolas Proust, James P. Stambuli | |
| 2:40 PM | 402 | Palladium catalyzed alkyne cross-coupling reactions promoted by zinc salts: Suppression of diyne byproducts Aaron D. Finke, Eric C. Elleby, Michael J. Boyd, Jeffrey S. Moore | |
| 3:00 PM | 403 | Palladium-catalyzed α-arylation of substituted cyclohexylester enolates: Diastereoselective construction of quaternary center Eric A. Bercot, Seb Caille, Tracy M. Bostick, Krishnakumar Ranganathan, Jensen Randy, Margaret M. Faul | |
| 3:20 PM | 404 | Probing the mechanism of the copper-catalyzed azide-alkyne cycloaddition using reaction progress kinetic analysis: In situ catalyst activation and other surprises Jason E. Hein, Valery V. Fokin | |
| 3:40 PM | 405 | Reactivity of group 6 nonheteroatom-stabilized carbene complexes toward nucleophiles Javier Santamaría, Aránzazu Gómez, Miguel Tomás | |
| 4:00 PM | 406 | Tungsten directed regio- and stereoselective umpolung of enamide addition reactions derived from 1,2-dihydropyridine complexes Daniel P Harrison, Michal Sabat, William H. Myers, W Dean Harman | |
| 4:20 PM | 407 | Unexpected solvent effects in dirhodium Lewis acid catalyzed 1,3-dipolar cycloadditions Richard J. Duffy, Michael P. Doyle | |
| 4:40 PM | 408 | Zinc-mediated palladium-catalyzed formation of carbon-sulfur bonds Chad C. Eichman, James P. Stambuli | |
Metal-Mediated Reactions and Syntheses -- Next Session
Symposium Grid -- Division of Organic Chemistry -- Session Listing
The 238th ACS National Meeting, Washington, DC, August 16-20, 2009