Methane-carbon dioxide reforming over Ni/CaO-ZrO2 catalyst

FUEL 20

Sun Nannan, Shaguar131@126.com1, Wen Xia2, Zhao Ning Sr., weiwei@sxicc.ac.cn3, Xiao Fukui2, Wei Wei, weiwei@sxicc.ac.cn4, and Sun Yuhan, yhsun@sxicc.ac.cn1. (1) State Key Laboratory Of Coal Conversion, Institute Of Coal Chemistry, 030001, Taiyuan, P.R.China, taiyuan, 030001, China, (2) Institute Of Coal Chemistry, Chinese academy of science, (3) State Key Laboratory of Coal Conversion Institute of Coal Chemistry, Taoyuan Nan lu 27#, Taiyuan, 030001, China, (4) the State Key Laboratory of Coal Conversion, Institute of Coal Chemistry Chinese Academy of Sciences, Taoyuan nan road 27#, Taiyuan, 030001, China
Carbon dioxide reforming of methane was investigated over Ni/CaO-ZrO2 catalyst derived from co-precipitation method. The catalyst showed both high catalytic activity and stability at the methane and carbon dioxide ratio of 1:1. The characterization confirmed that the nano-porous framework of as-prepared support together with the Ni-support interaction enhanced the dispersion of Ni, and then promoted the resistance to sintering under reaction condition. As a result, carbon deposition is prevented, which is important for the catalyst stability.
 

Advances in CO2 Conversion and Utilization
8:00 AM-12:10 PM, Sunday, August 16, 2009 Marriott Metro Center -- Salon A/B, Oral

Sci-Mix
8:00 PM-10:00 PM, Monday, August 17, 2009 Walter E. Washington Convention Center -- Hall D, Sci-Mix

Division of Fuel Chemistry

The 238th ACS National Meeting, Washington, DC, August 16-20, 2009