ORGN 675 |
The enantioselective synthesis of various C-6 substituted hexoses has been achieved in 4 steps. The succinct route relies on the highly enantioselective Noyori reduction, Achmatowicz reaction (an oxidative rearrangement of furfuryl alcohols to pyranones) and subsequent diastereoselective oxidation and reduction reactions. |
Heterocycles and Aromatics, Asymmetric Reactions and Syntheses and Total Synthesis of Complex Molecules
7:00 PM-9:00 PM, Wednesday, August 19, 2009 Walter E. Washington Convention Center -- Ballroom C, Poster
Division of Organic Chemistry |