Unique photophysical properties and reactivity of phenylacetylene derivatives containing the B-N bond pair

ORGN 290

Adam Marwitz, amarwitz@uoregon.edu and Shih-Yuan Liu, lsy@uoregon.edu. Department of Chemistry, University of Oregon, Eugene, OR 97403-1253
Diphenylacetylene (tolan) is an important building block in several areas of chemistry. We have prepared two tolan derivatives via replacement of one or both phenyl rings in tolan with the isosteric 1,2-dihydro-1,2-azaborine ring. B-N incorporation alters the optoelectronic properties of these conjugated organic scaffolds. The synthesis, characterization, and reactivity studies of our compounds will be discussed, with particular focus on photophysical properties.

 

Heterocycles and Aromatics
1:00 PM-5:20 PM, Monday, August 17, 2009 Walter E. Washington Convention Center -- 206, Oral

Division of Organic Chemistry

The 238th ACS National Meeting, Washington, DC, August 16-20, 2009