Microwave-induced stereocontrol of β-lactam formation with dihydrophenanthrenyl imine via Staudinger reaction

ORGN 649

Debasish Bandyopadhyay, bandyopad@utpa.edu, Department of Chemistry, University of Texas-Pan American, 1201 W. University Drive, Edinburg, TX 78539 and Bimal K. Banik, banik@panam.edu, Department of Chemistry, The University of Texas-Pan American, 1201 West University Drive, Edinburg, TX 78541.
Cycloaddition reaction of an imine derived from dihydrophenanthrenyl amine has been performed using automated microwave oven. Different aspects of â-lactam formation following Staudinger reaction have been studied. The presence of the polyaromatic group on nitrogen of the imine has significant role in controlling the stereochemistry of the â-lactam.

 

Heterocycles and Aromatics, Asymmetric Reactions and Syntheses and Total Synthesis of Complex Molecules
7:00 PM-9:00 PM, Wednesday, August 19, 2009 Walter E. Washington Convention Center -- Ballroom C, Poster

Division of Organic Chemistry

The 238th ACS National Meeting, Washington, DC, August 16-20, 2009