Synthesis and characterization of fullerooxazoles obtained from the reaction of fullerene trianions

ORGN 296

Xiang Gao, xgao@ciac.jl.cn, Fang-Fang Li, Ling Ni, and Wei-Wei Yang. State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, 5625 Ren Min Street, Changchun, 130022, China
A series of fullerooxazoles have been obtained from the reaction of fullerene trianions. The reaction shows regioselectivity for the formation of heterocycles, which is rationalized by the charge distribution on fullerene cage. The electrochemical and spectroelectrochemical properties of the obtained compounds are reported.
 

Heterocycles and Aromatics
1:00 PM-5:20 PM, Monday, August 17, 2009 Walter E. Washington Convention Center -- 206, Oral

Division of Organic Chemistry

The 238th ACS National Meeting, Washington, DC, August 16-20, 2009