ORGN 685 |
| The first organocatalytic kinetic resolution of 2-substituted ferrocenecarbaldehyde is reported. The use of aldol or Mannich reaction gives access to both enantiomers of starting material by using the same catalyst (L-proline). We have obtained selectivity factors up to 9,2. |
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Heterocycles and Aromatics, Asymmetric Reactions and Syntheses and Total Synthesis of Complex Molecules
7:00 PM-9:00 PM, Wednesday, August 19, 2009 Walter E. Washington Convention Center -- Ballroom C, Poster
Division of Organic Chemistry |