ORGN 684 |
| A convenient and novel oxazol-5-one addition to nitrostyrenes is reported. The reaction is catalyzed by tertiary amines yielding the corresponding adducts with total regio- and diastereoselectivity. The addition takes exclusively place at the C-2 position of oxazol-5-ones, furnishing diastereopure N,O-aminals. |
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Heterocycles and Aromatics, Asymmetric Reactions and Syntheses and Total Synthesis of Complex Molecules
7:00 PM-9:00 PM, Wednesday, August 19, 2009 Walter E. Washington Convention Center -- Ballroom C, Poster
Division of Organic Chemistry |