INORMonday, April 7, 2008

2:00 PM-5:50 PM Morial Convention Center -- Rm. 221, Oral
Frontiers in Organometallic Chemistry
Organizers:Bernadette T. Donovan-Merkert
Debbie C Crans
Presiding:Folami T. Ladipo
2:00 PMIron in a nitrogen ligand environment: Toward an FeIV nitride
Drew Buschhorn, Maren Pink, Hongjun Fan, Kenneth G. Caulton
2:20 PMInsights into the mechanism of reductive dehalogenation of chloroalkenes at cobalt centers from first-principles molecular dynamics simulations
Michael Bühl
2:40 PMMechanistic studies of the dehydrofluorination of fluorocarbons by titanium alkylidynes
Alison R. Fout, Brad C. Bailey, Deanna L. Miller, Jennifer L. Scott, Hongjun Fan, Maren Pink, Mu-Hyun Baik, Daniel J. Mindiola
3:00 PMUse of transition metal complexes with high d-electron counts for the 1,2-addition of C-H bonds across metal-heteroatom bonds as a strategy for C-H functionalization
T. Brent Gunnoe, Yuee Feng, John P. Lee, Josh Gurkin
3:20 PMIntermission
3:25 PMHigh-temperature controlled olefin polymerization behavior of titanium-based catalysts bearing arene-alkoxide and amide ligands
Folami T. Ladipo, Richard Eaves, Leon Dyers, Sean Parkin, Ryan R. Ketcham
3:45 PMHighly unsaturated cationic complexes of late transition metals
Oleg V. Ozerov, Claudia M. Fafard, Yanjun Zhu, Djamaladdin G. Musaev, Christos Douvris, Chun-Hsing Chen, Bruce M. Foxman, Lei Fan
4:05 PMAlkali-metal-mediated organotransitionmetalation: A method for directly attaching transition metals to aromatic frameworks
Robert E. Mulvey, Jan Klett, Victoria Blair
4:25 PMFormation of C-N, C-O and C-S bonds catalyzed by monomeric N-heterocyclic carbene supported Cu complexes with amido, alkoxo, aryloxo and sulfido ligands
T. Brent Gunnoe, Colleen Munro-Leighton, Samuel A. Delp
4:45 PMIntermission
4:50 PMMechanistic insights to the reactivity of neutral nickel salicylaldiminato alkyl complexes in aqueous solution
Andreas Berkefeld, Stefan Mecking
5:10 PMStructural elucidation of a nickel boryl complex
Debashis Adhikari, John C. Huffman, Daniel J. Mindiola
5:30 PMCatalytic carbon-hydrogen bond functionalization via in situ generated allyl and vinyl boronates
Vilhelm J. Olsson, Kalman J. Szabo

Frontiers in Organometallic Chemistry -- Next Session

Symposium Grid -- Division of Inorganic Chemistry -- Session Listing

The 235th ACS National Meeting, New Orleans, LA, April 6-10, 2008