Boron-doped and oxide-coated carbon nano-onions

FUEL 231

John P. Selegue, selegue@uky.edu and John D. Craddock, jdcrad2@uky.edu. Department of Chemistry, University of Kentucky, 125 Chemistry-Physics Building, Lexington, KY 40506-0055
Carbon nano-onions (CNOs), multi-layered giant fullerenes, may be the least studied new allotrope of carbon. In particular, their chemical reactivity remains largely unexplored. We report here on three aspects of CNO reactivity: (1) mechanochemical reactions of CNOs with KOH; (2) growth of metal and nonmetal oxides on CNO cores; and (3) attempts to incorporate boron into CNOs by incorporating boron-containing precursors into the underwater carbon-arc discharge synthesis. CNO products were characterized mainly by using thermogravimetric analysis (TGA) and electron microscopy (SEM).
 

Chemistry of Carbon Materials and Nanomaterials
8:30 AM-11:45 AM, Thursday, April 10, 2008 Morial Convention Center -- Rm. 240/241, Oral

Division of Fuel Chemistry

The 235th ACS National Meeting, New Orleans, LA, April 6-10, 2008