Reactions of atomic carbon with alkynes

CHED 430

Daniel B. Herrick, dherrick@colby.edu and Dasan M. Thamattoor, dmthamat@colby.edu. Department of Chemistry, Colby College, 5750 Mayflower Hill, Waterville, ME 04901
The reactions of alkynes with arc generated carbon atoms will be described. The ability of these reactions to produce cyclopropenylidenes will be examined. The computational investigation of these cyclic carbenes, using density functional methods, will be also discussed with respect to their structures and reactivity.