The photochemistry and electrochemistry of 4,N-dibutyl-1,8-naphthalimide

CHED 507

Derek M. Thomas, derekt72@uni.edu and Dr. Jeffrey Elbert, jeffrey.elbert@uni.edu. Department of Chemistry & Biochemistry, University of Northern Iowa, Cedar Falls, IA 50613

Irradiation of 4,N-dibutyl-1,8-naphthalimide resulted in one major photoproduct. Our starting material and 20 micro-liters of n-butylamine were irradiated. 4-amino-N-butyl-1,8-naphthalimide was created under conditions of water, ethanol, and 1X PBS buffer. Modifying the solvent concentration, time intervals, buffer pH, and adding n-butylamine all produced the same, single photoproduct. Proposed mechanisms will be presented and discussed.