Benzohydroximoyl halides have been used in synthetic schemes to produce oxime ethers of predictable E or Z stereochemistry.  We now report the synthesis of benzohydroximoyl halides of specific E or Z configuration containing a chiral N-alkoxy group.  These compounds are produced by synthesizing a chiral N-alkoxyphthalimide via a Mitsunobu reaction.  N-alkoxylamine is released from the phthalimide and reacted with benzoyl chloride to produce a chiral benzohydroxamate.  This hydroxamate can then be converted to a chiral hydroximoyl halide.  The stereochemistry of the resulting benzohydroximoyl halide will be discussed along with potential reaction schemes to convert it to a chiral oxime ether.