Stability of palladium nanoparticles under simulated environmental conditions

CHED 1131

Ali M. Bramson, Department of Soil Science, University of Wisconsin, 1555 Observatory Dr, Madison, WI 53706, Kevin M. Metz, kmmetz@wisc.edu, Environmental Chemistry and Technology, University of Wisconsin-Madison, 1555 Observatory Dr, Madison, WI 53706, and Joel A. Pedersen, joelpedersen@wisc.edu, Department of Soil Science and Molecular and Environmental Toxicology Center, University of Wisconsin-Madison, 1525 Observatory Drive, Madison, WI 53706-1299.
Nanoscale palladium is commonly used as a catalyst and holds promise for many other applications. Environmental exposure to nanoscale palladium could have profound effects due to its reactivity. We investigated the stability of palladium nanoparticles (PdNPs) under simulated oxidative environmental conditions. We synthesized PdNPs via a modified aqueous reduction procedure and examined their stability using an in vitro biomimetic oxidative assay. Palladium nanoparticle transformation was characterized using a variety of analytical methods. Our results will be presented.