PHYS 546 |
The Belousov-Zhabotinsky (BZ) reaction is the prototype oscillatory chemical reaction. A typical reaction includes the autocatalytic species bromous acid, an inhibitory species Br-, a catalyst (here ferroin/ferriin (Fe(phen)3+2/+3) or Mn+2/+3), H+, malonic acid (MA) and its halogenated form. Catalytic oxidation of MA provides free energy to drive oscillations and a source of Br- on a slow time scale. Typical reagent mixtures demonstrate either large amplitude limit-cycle oscillations or excitable behavior (an equilibrium state which can be driven far from equilibrium by a suitable small perturbation such before returning to equilibrium), depending upon initial concentrations. Showalter and Noyes found that the certain BZ reactions displayed oscillatory behavior when initial concentrations satisfied [H+][Br-] < 0.045 M2 . We show from experiment and simulations that steady states (stable or unstable) scale universality with Showalter-Noyes limit, and modified limits characterizes the boundary in ferroin and Mn catalyzed reactions. Partially supported by NSF CHE-0515691.
|
|
PHYS Poster Session - General Theory
7:30 PM-10:00 PM, Wednesday, April 9, 2008 Morial Convention Center -- Hall A, Poster
Division of Physical Chemistry |