Oscillatory/excitable boundary in the Belousov-Zhabotinsky reaction: The Showalter-Noyes limit, scaling and universality

PHYS 546

Harold M Hastings, Harold.Hastings@Hofstra.edu1, Richard J. Field, ch_rjf@selway.umt.edu2, Sabrina G Sobel, Sabrina.G.Sobel@hofstra.edu3, Dominick Bongiovi3, Brianna Burke3, David Miller1, and Daniel Richford1. (1) Department of Physics and Astronomy, Hofstra University, CHPHB 102, 151 Hofstra University, Hempstead, NY 11549, (2) Department of Chemistry, The University of Montana, Missoula, MT 59812, (3) Department of Chemistry, Hofstra University, 106 Chemistry & Physics Bldg, 151 Hofstra Unversity, Hempstead, NY 11549-1510

The Belousov-Zhabotinsky (BZ) reaction is the prototype oscillatory chemical reaction.  A typical reaction includes the autocatalytic species bromous acid, an inhibitory species Br-, a catalyst (here ferroin/ferriin (Fe(phen)3+2/+3) or Mn+2/+3), H+, malonic acid (MA) and its halogenated form.  Catalytic oxidation of MA provides free energy to drive oscillations and a source of Br- on a slow time scale.  Typical reagent mixtures demonstrate either large amplitude limit-cycle oscillations or excitable behavior (an equilibrium state which can be driven far from equilibrium by a suitable small perturbation such before returning to equilibrium), depending upon initial concentrations.  Showalter and Noyes found that the certain BZ reactions displayed oscillatory behavior when initial concentrations satisfied [H+][Br-] < 0.045 M2 .  We show from experiment and simulations that steady states (stable or unstable) scale universality with Showalter-Noyes limit, and modified limits characterizes the boundary in ferroin and Mn catalyzed reactions.  Partially supported by NSF CHE-0515691.

 

 

PHYS Poster Session - General Theory
7:30 PM-10:00 PM, Wednesday, April 9, 2008 Morial Convention Center -- Hall A, Poster

Division of Physical Chemistry

The 235th ACS National Meeting, New Orleans, LA, April 6-10, 2008