Understanding, developing and optimizing the chemistry of carbon dioxide capture

BMGT 4

Graeme D Puxty, Graeme.Puxty@csiro.au, Division of Energy Technology, CSIRO, PO Box 330, Newcastle NSW 2300, Australia

Electricity generation from fossil fuel combustion is a major source of CO2 emissions (~32% of global CO2 emissions). To effectively reduce CO2 emissions in the short to medium term requires CO2 capture and storage as a part of the solution.

The CSIRO Division of Energy Technology has undertaken a major CO2 research program covering many aspects of the technology. On the laboratory scale, the chemical reactions involved in CO2 capture and release by chemical absorption are being investigated and modelled to identify where and how improvements in efficiency can be made. Over 100 commercially available and newly synthesised amines have been screened for their ability to capture CO2. A number of previously untested amines have been identified that give improved CO2 capture capacity over the existing industry standard, monoethanolamine (MEA). This has led to the identification of unique structural features common to the top performing amines.