Phosphinomethylamines, synthesis of a simple hydrogenase mimic

CHED 1209

Scott A. Heston, saheston@fortlewis.edu and Monte L. Helm, helm_m@fortlewis.edu. Chemistry Department, Fort Lewis College, 1000 Rim Drive, Durango, CO 81301
We will report the synthesis of Ph2PCH2NPh2, a simple hydrogenase mimic. Additionally, we will report the synthesis of the Ni(II) complex, [Ni(triphos)CH3CN](BF4)2 (triphos = PhP(CH2CH2PPh2)2) and its initial metal-coordination reactions with Ph2PCH2NPh2.