Hybrid metal-semiconductor nanoparticles: A new type of functional materials

PHYS 99

Uri Banin, banin@chem.ch.huji.ac.il, Ronny Costi, costi@chem.ch.huji.ac.il, Einat Elmalem, einat@chem.ch.huji.ac.il, and Asaf Salant, salant@chem.ch.huji.ac.il. Institute of Chemistry and the Center for Nanoscience and Nanotechnology, Hebrew University of Jerusalem, Givat Ram, Jerusalem, 91904, Israel
An important frontier in nano-materials research concerns nanoparticles with different materials in the same nanostructure as means of increasing functionality. One particularly interesting combination of materials is that of a metal and semiconductor in the same nanoparticle where metal tips grown on a semiconductor rod can provide anchor points for electrical connections and for self assembly. We report the growth of various metals onto semiconductor dots and rods. Other growth modes of metal-semiconductor hybrid particles will be discussed. Such systems manifest a unique model for a metal-semiconductor nanoscale junction. A fundamental and intriguing problem associated with such systems is its optical and electronic properties. The electronic properties of metal-semiconductor nanojunctions were investigated by several methods including scanning tunneling spectroscopy of the gold-tipped CdSe rods and by electrostatic force microscopy. The potential use of metal-semiconductor hybrid nanoparticles as novel photocatalysts active in the visible range will also be discussed.
 

Nanostructured Materials
8:20 AM-12:00 PM, Monday, April 7, 2008 Morial Convention Center -- Rm. 338/339, Oral

Division of Physical Chemistry

The 235th ACS National Meeting, New Orleans, LA, April 6-10, 2008