Dynamic restructuring of au(111)

AEI 38

Weiwei Gao, wgao@fas.harvard.edu1, Ling Zhou, lingzhou@seas.harvard.edu2, Dilini S. Pinnaduwage, pinnaduw@fas.harvard.edu2, Byoung Kuon Min1, Monika Biener, scherlchen@yahoo.com1, and Cynthia M. Friend1. (1) Department of Chemistry & Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, MA 02138, (2) School of Engineering and Applied Sciences, Harvard University, Pierce Hall, 29 Oxford St., Cambridge, MA 02138
Motivated by the immerging applications of gold catalysts, we have been studying nanoscale restructuring of Au(111) surface upon interaction with electronegative molecules such as O, S and Cl. Surface restructuring with different ordering and incorporation of Au atoms into a growing surface compound phase have been observed and studied by scanning tunneling microscopy combined with temperature programmed desorption, X-ray photoelectron spectroscopy and low energy electron diffraction. Our studies provide new insight into the dynamic surface chemistry on Au.