INOR 109 |
Tetradentate bis(imine-quinaldine) ligands coordinate to the divalent metal ions Zn(II) and Ni(II) in a number of modes. Zinc chloride gives single-stranded M-dihelicates, while zinc triflate can lead to ligand reduction and a mononuclear P-helical complex with pi-pi-stacked ligand sidearms. Nickel iodide gives mononuclear complexes with three donors coordinated or dinuclear complexes with a single ligand wrapped around a Ni2I4 core. Nickel triflate gives a double-stranded monohelix with two partially hydrolyzed tridentate ligands. |
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Characterization and Applications of Coordination Compounds
1:30 PM-5:50 PM, Sunday, August 19, 2007 BCEC -- 213, Oral
Division of Inorganic Chemistry |