PETR 74 |
| We present experimental and computational results regarding the properties of mass-selected clusters supported on TiO2. We examine the structure of the Aun (n = 1--7) clusters, their diffusion, their interaction with CO and O2, CO oxidation, the charge exchange between them and the substrate and the role of co-adsorption. We show that most of the results can be understood as a consequence of the overlap of the frontier orbitals. |
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Mechanism in Homogeneous and Heterogeneous Catalytic Epoxidation
8:30 AM-11:40 AM, Tuesday, August 21, 2007 Boston Park Plaza -- Whittier Rm, Oral
Division of Petroleum Chemistry |