Novel synthesis of Janus particles from 1-D polymer substrates

COLL 167

Chi-Chih Ho, n5694107@mail.ncku.edu.tw and Changshu Kuo. Department of Materials Science and Engineering, National Cheng-Kung University, No.1, Dasyue Rd., tainan city, 701, Taiwan
A novel synthetic approach was successfully demonstrated as the efficient fabrication of Janus particles. Instead of utilizing two-dimensional plane surfaces, one-dimensional polymer fibers provided even more interfacial area to confine or encapsulate zero-dimensional colloids. A polymer-based electrospinning technique capable of making polymeric fiber mats with desired composites was employed to produce substrates with high surface-to-volume ratio. Silica colloids were adsorbed on the surface of polymer fibers, followed by the thermally-induced embedment under the precise temperature manipulation. Hemispheric surface modification of embedded silica colloids was then conducted by silanization with (3-aminopropyl)trimethoxysilane. Uniform functionalization of Janus particles were further confirmed by the attachment of gold nanoparticles onto the amino-enriched hemispheric surfaces. Fabrication and characterization of Janus particles were discussed.