Gd(III)-based bile acid conjugates for dual magnetic resonance and fluorescence imaging

MEDI 100

Sooyoun Lim, chong@iit.edu, Xiang Ma, ma@iit.edu, and Hyun-Soon Chong. Chemistry Division, Biological, Chemical, and Physical Sciences Department, Illinois Institute of Technology, 3101 S. Dearborn St, LS 182, Chicago, IL 60616
Magnetic resonance imaging (MRI), a non-invasive and high resolution imaging technique has become a powerful tool in diagnostic medicine. The development of the adequate synthetic bifunctional chelates that can hold contrast enhancing metal while being conjugated to a targeting moiety is a critical step for disease-specific MRI. The bifunctional versions of the promising Gd(IIII) chelate, NETA, C-NETA and C-NE3TA have been synthesized and conjugated to a liver targeting moiety, bile acid. The bile acid-ligand conjugates after being complexed with gadolinium(III) have been evaluated for their T1 relaxivities, cellular uptakes, MRI, and fluorescence imaging. The synthesis and in vitro evaluation of Gd(III) based bile acid conjugates as dual MR and flurorescence imaging agents will be reported.
 

Poster Session
7:00 PM-9:00 PM, Sunday, August 19, 2007 BCEC -- Exhibit Hall - B2, Poster

Division of Medicinal Chemistry

The 234th ACS National Meeting, Boston, MA, August 19-23, 2007