INOR 720 |
| Polyoxometalates (POMs)are an outstanding class of inorganic building blocks for the construction of organic-inorganic hybrid materials because of their intriguing structural chemistry, unexpected reactivities and potential applications. Bipyridine(bipy) is a rod-like molecule commonly used as a versatile ligand, and the d10 ions generally show variable coordination numbers and tunable coordination spheres, which can build metal-organic polymer subunits to modify POMs. Herein, three novel POMs obtained by hydrothermal synthesis are reported: 1D {[Cu(4,4-bipy)]3[HGeMo12O40]}.0.5H2O (1), modified by three-track Cu(bipy) chains; 2D {[Cu(4,4'-bipy)]3[W6O19]}.4H2O (2), modified by four-track Cu(bipy) chains and 3D {AsMo12O40(VO)[VO(H2O)]}.[Cu(4,4'-bipy)5.H2O (3), modified by six-track Cu(bipy) chains. Their structural differences reveal that the influence of the size of POMs on the assembly of the solid structures of the POM-based hybrid materials is through changing the number of co-parallel multichains of Cu-N coordination polymer and the dimension of the organic-inorganic hybrid materials
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Polyoxometalates and Related Clusters in Chemistry and Nanoscience
7:00 PM-10:00 PM, Tuesday, August 21, 2007 BCEC -- Exhibit Hall - B2, Poster
Division of Inorganic Chemistry |
