Theory of metallic bonding

CHED 508

Yuriy Gankin, Yuriy_gankin@hotmail.com, Elsevier MDL, 30 Corporate Drive, Suite 400, Burlington, MA 01803 and Victor Gankin, victor_gankin@hotmail.com, Institute of Theoretical Chemistry (ITC), 8 Shrewsbury Green Drive, , Fax: 508-799-2776, Shrewsbury, MA 01545.
According to J.N. Spencer (JCE No. 3 p.182 1991) base of quantum-chemical interpretations are ‘unteachable'. We have developed an approach that helps explaining major chemical phenomena (covalent bonding, chemical kinetics and catalysis) without introducing quantum chemical entities. Our approach and a General Chemistry text book synopsis utilizing it are presented at www.ITChem.com. Based on that approach we have developed a theory of metallic bonding and explained the differences between bonds in metals and non-metallic compounds. While atoms of non-metals are connected via static two-electron covalent bonds, atoms in solid metals are linked by dynamic one-electron bonds. We have built quantitative models that explain how that bonding difference determines dissimilarity between properties (primarily thermo and electrical conductivity) of metals and non-metals.
 

General Papers
1:00 PM-4:05 PM, Thursday, August 23, 2007 Seaport -- Plaza A, Oral

Division of Chemical Education

The 234th ACS National Meeting, Boston, MA, August 19-23, 2007