Assessment of concentrations and human exposure of polybrominated diphenyl ethers in outdoor and indoor air of homes and occupational settings in Greece

ENVR 181

Euripides G. Stephanou, stephanou@chemistry.uoc.gr and Manolis Mandalakis, mandalakis@chemistry.uoc.gr. Environmental Chemical Processes Laboratory (ECPL), Department of Chemistry, University of Crete, GR-71003 Voutes-Heraklion, Greece
Airborne polybrominated diphenyl ethers (PBDEs) were measured in specialized occupational settings, homes and urban outdoor air in Greece. The geometric mean concentrations of ∑PBDE (sum of 19 congeners) in offices (205 pg m−3), internet cafes/computer rooms (127 pg m−3) and computers/electronics shops (85 pg m−3) were significantly higher than those in furniture stores (12 pg m−3), homes (8 pg m−3) and outdoor air (18 pg m−3). In one extreme case (public office), a ∑PBDE concentration of 10,848 pg m−3 was detected. Principal component analysis revealed substantial differences in the PBDE congener profiles among furniture stores, internet cafes/computer rooms and outdoor air. It was further inferred that volatilization from electronic appliances and/or outdoor air should be the main source of PBDEs inside houses and offices, while emissions from furniture should be less important. The daily ∑PBDE inhalation intake estimated for the employees of the four occupational settings ranged from 0.2 to 1.4 ng day−1 and it was significantly lower than the expected dietary intake (~77 ng day−1). Although inhalation generally represented a small fraction of the overall daily exposure to PBDEs (~1%), the results from the heavily contaminated office indicated that the intake from this route (65 ng day−1) might, in some cases, be as important as diet.
 

Symposium Honoring Dr. Walter Giger
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Sci-Mix
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Division of Environmental Chemistry

The 234th ACS National Meeting, Boston, MA, August 19-23, 2007