Liquid crystalline co-elastomers displaying one-way shear shape memory

PMSE 153

Kelly A. Burke, kelly.burke@case.edu and Patrick T. Mather, patrick.mather@case.edu. Department of Macromolecular Science and Engineering, Case Western Reserve University, 2100 Adelbert Road, Cleveland, OH 44106

The preparation of mixed mesogen liquid crystalline elastomers was achieved by hydrosilylation of diene mesogens (5tB and 5Me) and a tetravinyl crosslinker with hydride-terminated poly(dimethylsiloxane). The thermal and mechanical properties of the resulting 5tB-5Me elastomers were found to vary significantly with elastomer composition. While the E(05tB-1005Me) elastomer has distinct glass transition and clearing temperatures, the E(1005tB-05Me) elastomer shows only a Tg, suggesting that these materials are isotropic. One-way shear shape memory (SSM) cycles of all the elastomers studied revealed excellent shear strain fixing – despite high compliance below the fixing temperature – and heat-induced recovery. In addition some elastomers revealed ordering-induced shear strain when cooling below the isotropization temperature under constant stress, indicating soft elastic behavior and the potential for two-way (reversible) shape memory due to ordering. We envision multiple applications that exploit shear shape memory (SSM) behavior, including torsional mechanical actuators and smart journal bearings.

 

 

ICI Student Award Symposium
8:30 AM-11:55 AM, Tuesday, August 21, 2007 Westin Boston Waterfront -- Grand Ballroom D, Oral

Division of Polymeric Materials: Science & Engineering

The 234th ACS National Meeting, Boston, MA, August 19-23, 2007