Schmidt-type rearrangement reactions of alkylarylhydroximoyl azides

ORGN 893

Artie S. McKim, amckim@gaylordchem.com, Gaylord Chemical Corporation, 209 Industrial Parkway, Bogalusa, LA 70427 and Debra D. Dolliver, ddolliver@selu.edu, Department of Chemistry & Physics, Southeastern Louisiana University, SLU 10878, Hammond, LA 70402.
The ability of O-alkylarylhydroximoyl azides to undergo Schmidt-type rearrangements to produce unusual carbodiimidoyl ethers and their hydrolysis products will be reported. A series of alkylarylhydroximoyl azides having varying aromatic ring substituents were investigated under acid-catalyzed and photochemical conditions.

 

Combinatorial, Parallel and Process Chemistry, Heterocycles, Aromatics, New Reactions and Methodology
8:00 PM-10:00 PM, Wednesday, August 22, 2007 BCEC -- Exhibit Hall - B2, Poster

Sci-Mix
8:00 PM-10:00 PM, Monday, August 20, 2007 BCEC -- Exhibit Hall - B2, Sci-Mix

Division of Organic Chemistry

The 234th ACS National Meeting, Boston, MA, August 19-23, 2007