ORGN 556 |
| Transition metal pi-complexes have long proven to be valuable reagents for synthetic organic chemists, given the myriad of ways in which they can modify the organic ligand. The body of known information about radical reactions in organic synthesis has also shown dramatic growth over the last 25 years. The subset of these two reaction families, namely radical reactions of transition metal pi complexes, has received only modest attention. We have recently demonstrated radical addition reactions with styrene chromiumtricarbonyl (Eq. 1) and dihydronaphthalene rutheniumcyclopentadienide hexafluorophosphate (Eq. 2).
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Physical Organic Chemistry, Metal-Mediated Reactions, Asymmetric Reactions and Syntheses
8:00 PM-10:00 PM, Tuesday, August 21, 2007 BCEC -- Exhibit Hall - B2, Poster
Division of Organic Chemistry |
