Preparation and applications of novel fluorinated oligomeric nanoparticles

COLL 186

Takurou Kariya, hideosaw@cc.hirosaki-u.ac.jp1, Masaki Mugisawa1, Takahisa Oya2, Shin-ichi Ogino2, and Hideo Sawada, hideosaw@cc.hirosaki-u.ac.jp1. (1) Department of Frontier Materials Chemistry, Hirosaki University, Hirosaki-City, 036-8561, Japan, (2) Kansai Paint Co., Ltd, Hiratsuka-City, 254-8562
Novel cross-linked fluorinated oligomeric nanoparticles were prepared by the reaction of adipic acid dihydrazide with fluoroalkyl end-capped N-(1,1-dimethyl 3-oxobutyl)acrylamide oligomer [Rf-(DOBAA)n-Rf]. These fluorinated nanoparticles thus obtained were not able to interact with hibitane as a guest molecules. However, Rf-(DOBAA)n-Rf oligomeric aggreagtes could react with hibitane to afford the corresponding oligomer/hibitane nanocompistes with a good dispersibility and stability in methanol.
 

Fundamental Research in Colloid and Surface Chemistry
6:00 PM-8:00 PM, Monday, August 20, 2007 BCEC -- East Registration, Poster

Division of Colloid & Surface Chemistry

The 234th ACS National Meeting, Boston, MA, August 19-23, 2007