Biomass as a source of photopolymerizable monomers and polymers

POLY 391

James V. Crivello, crivej@rpi.edu, Department of Chemistry and Chemical Biology, Rensselaer Polytechnic Institute, 110 8th Street, Troy, NY 12180
Several classes of monomers derived from biomass were either prepared or used directly as isolated from their plant sources in photoinitiated cationic polymerizations. Among these monomers are epoxidized vegetable oils, terpene epoxides, epoxidized terpene alcohols and vinyl ether-modified carbohydrates and polyols. The use of cationic photopolymerization to prepare polymers is both environmentally and energetically attractive. Moreover, the recent discovery of a dye that permits the use of solar radiation to conduct these polymerizations further increases their attractiveness and potential utility.
 

Polymers from Renewable Resources
1:25 PM-5:25 PM, Tuesday, August 21, 2007 Westin Boston Waterfront -- Douglas, Oral

Division of Polymer Chemistry

The 234th ACS National Meeting, Boston, MA, August 19-23, 2007