INORWednesday, March 28, 2007
9:00 AM-12:00 PM McCormick Place Lakeside -- Room E255, Level 2, Oral
General Inorganic and Organometallic Chemistry
Organizers:Bernadette T. Donovan-Merkert
Debbie C Crans
Presiding:Helena C. Malinakova
9:00 AM1135Olefin deformation and its importance in metal-olefin bond strengths
David L. Cedeņo, Darin N. Schlappi, Richard Sniatynsky, Cole R. Hexel, Julio Martinez
9:20 AM1136Sigma-CAM mechanism: ς-Complex assisted metathesis at late transition metals
Robin N. Perutz, Sylviane Sabo-Etienne
9:40 AM1137Allylpalladium(IV) intermediate in the synthesis of highly substituted benzoxepines and benzopyrans via reactions of stable pallada(II)cycles with allyl bromides
Helena C. Malinakova, Ruiyun Guo, Victor W. Day, Piyali Datta-Chaudhuri, Janelle L. Portscheller
10:00 AM1138Iridium-catalyzed dimerization of alkynes: A mechanistic study revealing factors governing the energetics of C-C reductive elimination
Alan S. Goldman, Rajshekhar Ghosh, Thomas J. Emge, Patrick D. Achord, Xiawei Zhang, Karsten Krogh-Jespersen
10:20 AM Intermission
10:40 AM1139Cyclometalated iridium and platinum metal complexes with non-innocent ligands
Bhavna Hirani, Mark E. Thompson
11:00 AM1140Quinone-annulated N-heterocyclic carbenes and their transition metal complexes
Christopher W. Bielawski
11:20 AM1141Selective decarbonylation of aldehydes by a pincer rhodium(I) complex: The role of steric and electronic effects
Kuo-Wei Huang, David C. Grills, Joseph H. Han, Charles B. Musgrave, Etsuko Fujita
11:40 AM1142Synthesis and reactivity of group (V) PNP complexes
Uriah J. Kilgore, Xiaofan Yang, John Tomaszewski, John C. Huffman, Daniel J. Mindiola

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The 233rd ACS National Meeting, Chicago, IL, March 25-29, 2007