Constructing a green alternative to a traditional physical chemistry experiment, the moderate-resolution infrared spectra of carbon dioxide: Analysis of weak absorption bands

CHED 1382

Catherine Marie Clark, caclark@linfield.edu and Christopher Robert Braden, cbraden@linfield.edu. Department of Chemistry, Linfield College, 190 SE Brumback, Unit 2239, McMinnville, OR 97128
In order to demonstrate the potential for CO2 gas to replace HCl gas in a common physical chemistry experiment, FTIR spectroscopy was performed on CO2. Techniques such as the inclusion of P2O5 in the gas cell were applied to reduce interference by water. This allowed for the resolution of bands resulting from rotational-vibrational coupling, which are necessary in determining molecular constants.