Energetic analysis of base-pair stability and DNA decamers containing 7,8-dihydro-8-oxoguanine

CHED 1303

Tyler Steele, tyler.steele@richmond.edu, Carol A. Parish, cparish@richmond.edu, and Michelle Hamm, mhamm@richmond.edu. Department of Chemistry, University of Richmond, 28 Westhampton Way, Richmond, VA 23173
DNA base-pair mutations have been implicated in aging and cancer. 8-Oxo-2'-deoxyguanosine (OdG) is an abundant DNA lesion for which analogues have been developed and experimentally tested. In this work we have utilized the OPLSAA/GBSA(water) molecular mechanics method to analyze and compare the energetics of normal (dG:dC and dA:dT) and damaged (XdG(anti):dC and XdG(syn):dA where X=O, C, Cl, Br and I) base-pairs. A comparison of structural and geometrical differences and similarities will be presented. In addition, the structural and energetic effects of various base pairs will be examined using a model 10 unit DNA strand.
 

Undergraduate Research Poster Session: Medicinal
2:00 PM-4:00 PM, Monday, March 26, 2007 Hyatt Regency Chicago -- Riverside Center, Poster

Division of Chemical Education

The 233rd ACS National Meeting, Chicago, IL, March 25-29, 2007