Quantification of photochemically produced hydroxyl radical from chlorinated quinone pesticides

CHED 1135

Pamela P. Vaughan, pvaughan@uwf.edu, Katherine Davis, and Dayoung An. Chemistry, University of West Florida, 11000 University Parkway, Pensacola, FL 32514
Use of several radical trapping techniques including benzoic acid, nitroxide/DMSO, and nitroxide/methane methods have been employed to quantify the extent of photo-reactivity under solar simulated conditions. Preliminary evidence supports photochemical formation of highly reactive hydroxyl radical from the reaction of chlorinated quinone pesticides with water. Compounds of interest include the chlorinated pesticides, dichlone (2,3-dichloro-1,4-napthoquinone) and chloranil (tetrachloro-1,4-benzoquinone). Rates of photochemically produced hydroxyl radical will be presented as well as proposed degradation products for these pesticides.