Encapsulation of CdTe Quantum dots by thiolated chitosan nanoparticles

AGFD 88

Gye Hwa Shin, winnie19@eden.rutgers.edu, Qiang Wang, QWANG@AESOP.Rutgers.edu, Jun Tae Kim, jtkim520@eden.rutgers.edu, and Qingrong Huang, qhuang@aesop.rutgers.edu. Department of Food Science, Rutgers, The State University of New Jersey, 65 Dudley Rd., New brunswick, NJ 08901
Recently, Quantum dots (QDs) have shown great potential for biological imaging and drug/food delivery applications. To be used for drug delivery applications, the QDs need to be able to sustain acidic pH (i.e. ~2.0). Although water-soluble CdTe quantum dots can be directly synthesized in aqueous solutions, most of the current reported QDs are not stable at pH<4.0. In this paper, we report a new method of preparing stable QDs using chitosan-thioglycolic acid (TGA) conjugated nanoparticles. First, chitosan, a linear copiolymer of beta(1-4) linked 2-acetamido-2-deoxy-beta-D-glucopyranose and 2-amino-2-deoxy-beta-D-glycopyranose, is chemically modified with thiol (-SH) group. The structure and properties of chitosan-thioglycolic acid conjugated QDs are studied by FT-IR, dynamic light scattering, fluorescence spectroscopy, and tapping mode atomic force microscopy (AFM). Our results show that encapsulated QDs are stable even in low pH condition.
 

General Posters
1:00 PM-3:00 PM, Monday, 11 September 2006 Moscone Center -- Hall D, Poster

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8:00 PM-10:00 PM, Monday, 11 September 2006 Moscone Center -- Hall D, Sci-Mix

Division of Agricultural & Food Chemistry

The 232nd ACS National Meeting, San Francisco, CA, September 10-14, 2006