Carbonylation in ionic liquid media

TECH 10

Mary K. Moore, mkmoore@eastman.com, R. M. Moncier, Gerald C. Tustin, gctustin@eastman.com, and J. R. Zoeller. Research Laboratories, Eastman Chemical Company, P.O. Box 1972, Kingsport, TN 37662-5150
Conducting the carbonylations in ionic liquid media allows some unique modes of operation. For example, when the rhodium catalyzed carbonylation of methanol to acetic acid is conducted in the non-volatile ionic liquids, the process can be operated in a vapor a take-off mode of operation, which eliminates several units of operation and catalyst recovery concerns while improving reaction rates. Additional benefits of employing an ionic liquid in carbonylations are becoming evident as the system continues to be investigated. A number of these advantages will be discussed with emphasis on the carbonylation of methanol.
 

General Papers
1:30 PM-5:55 PM, Monday, 11 September 2006 S.F. Downtown Courtyard by Marriott -- Soma 3, Oral

Sci Mix
8:00 PM-10:00 PM, Monday, 11 September 2006 Moscone Center -- Hall D, Sci-Mix

Division of Chemical Technicians

The 232nd ACS National Meeting, San Francisco, CA, September 10-14, 2006