ANYL 345 |
| Silica beads with average diameters of 40 – 600 nm were prepared and Ru(bpy)32+ complexes were incorporated into the beads. These beads were coated by silver layer-by-layer to generate porous but continuous metal nanoshells. The thicknesses of these metal shells were 5 – 50 nm. Emission band from the dyes in the silica cores was more narrow and intensity was enhanced with an growth of silver shell thickness due to coupling of the emission light from Ru(bpy)32+ in the cores with the metal plasmon from the silver shells. The enhancement of emission intensity was also dependent on the size of silica core showing that the enhancement efficiency decreased with increasing the size of silica bead. Lifetime measurements support the coupling mechanism between the dye and metal shell. This study can be used to develop novel dye-labeled metal particles with bright and narrow emission bands. |
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Analytical Approaches: Various Techniques and Applications
1:30 PM-4:00 PM, Thursday, 14 September 2006 Moscone Center -- Room 124, Oral
Division of Analytical Chemistry |