Synthesis of fluorinated sulfur-containing heterocycles from polynitroaromatic compounds

FLUO 24

Sergei G. Zlotin, zlotin@ioc.ac.ru1, Pavel G. Kislitsyn, kislitsyn_pavel@mail.ru1, Fedor A. Kucherov, greemted@mail.ru1, Yuri A. Strelenko, strel@ioc.ac.ru1, Alexander A. Astrat'ev, alcen@nevsky.net2, and Andrei A. Gakh, gakhaa@ornl.gov3. (1) Russian Academy of Sciences, N. D. Zelinsky Institute of Organic Chemistry, Leninsky Pr. 47, Moscow, 119991, Russia, (2) St. Petersburg Institute of Technology, SKTB "Technolog", Sovetsky pr. 33a, St. Petersburg, 193177, Russia, (3) Oak Ridge National Laboratory, Oak Ridge, TN 37831-6242
New synthetic approach for preparation of fluorinated benzo[d]isothiazoles, benzo[d]isothiazol-3(2H)-ones and benzo[b]thiophenes from available 2,4-di- and 2,4,6-trinitrotoluenes has been developed. The synthesis entails oxidation of the polynitrotoluenes to corresponding polynitrobenzoic acids with aqueous nitric acid at high temperature and pressure, stepwise displacement of the nitro groups in the 2,4-di- and 2,4,6-trinitrobenzamides (-nitriles) with S-, O-, and F- nucleophiles followed by the ring closure. Fluoro- or trifluoroethoxy- denitration of the nitroheterocycles was also employed in some cases. Among prepared compounds are fluorinated analogs of antiviral agents and enzyme inhibitors. The proposed methodology may be considered as an approach to the chemical utilization of polynitroaromatic compounds for the synthesis of valuable chemical products. The research was sponsored by the Global IPP program. Oak Ridge National Laboratory is managed and operated by UT-Battelle, LLC, under contract DE-AC05-00OR22725 for the U.S. Department of Energy. Contribution 23, the Discovery Chemistry Project.
 

Fluorinated Heterocycles
1:30 PM-4:55 PM, Monday, 11 September 2006 San Francisco Marriott -- Salon 5, Oral

Division of Fluorine Chemistry

The 232nd ACS National Meeting, San Francisco, CA, September 10-14, 2006