INOR 350 |
| Two general methods were developed for the synthesis of alkali metal salts of 2-substituted-1,2-oxaborolides. 2-Phenyl-1,2-oxaborolide was converted to Cp*Ru complex and to Mn(CO)3 complex, in which the metals are 5-bound to the ligand. For the first time, 2-substituted-1,2-oxaborines were successfully prepared through ring-expansion reaction of 1,2-oxaborolide and methylene chloride with BuLi as base. The coordination chemistry and aromatic characters as well as Diels-Alder reactions of oxaborines were also investigated. |
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Polyfunctional Organoboranes: From Molecules to Materials
7:00 PM-10:00 PM, Sunday, 10 September 2006 Moscone Center -- Hall D, Poster
Division of Inorganic Chemistry |