Adsorption of As(III) on mesoporous titania and Ti-containing mesoporous silica molecular sieve

ENVR 150

Dongsuk Han, ironhan@tamu.edu and Bill Batchelor, bill-batchelor@tamu.edu. Department of Civil Engineering, Texas A&M University, College Station, TX 77843-3136
In order to enhance treatment technologies for As(III) and meet stringent maximum contaminant level (MCL) for drinking water, new technologies are urgently required. In this study, As(III) removal using mesoporous titania (MT) and titanium containing mesoporous silica molecular sieve (Ti-SBA-15) was investigated. Unlike other conventional adsorbents, these mesoporous adsorbents (MAs) with nano-sized transition metal can provide higher surface area, large pore volume, well-ordered structure framework and high surface functional density due to their highly regular nanopores. The kinetic results showed that fast uptake of As(III) occurred and, subsequently, fast equilibrium between As(III) and MAs in solution was reached within almost 5 minutes. The isotherm test indicated that MT had higher sorption capacity than Ti(x)-SBA-15. In pH adsorption envelope of As(III), the higher removal efficiency of As(III) occurred at the pH ranges of 7–10 and 4–6.5 for MT and Ti(25)-SBA-15, respectively.
 

General Papers
6:00 PM-8:00 PM, Wednesday, 13 September 2006 Moscone Center -- Hall D, Poster

Sci-Mix
8:00 PM-10:00 PM, Monday, 11 September 2006 Moscone Center -- Hall D, Sci-Mix

Division of Environmental Chemistry

The 232nd ACS National Meeting, San Francisco, CA, September 10-14, 2006