Polystyrene-ZnO hybrid nanoparticles with core-shell morphology

POLY 496

Mukesh Agrawal, muk_iitd@yahoo.com1, Andrij Pich2, Smrati Gupta3, Nick E. Zafeiropoulos3, and Manfred Stamm, stamm@ipfdd.de1. (1) Leibniz Institut für Polymerforschung, Dresden e.V, Hohe strasse 6, Dresden, 01069, Germany, (2) Instituts für Makromolekulare Chemie und Textilchemie, Technische Universität Dresden, Mommsenstr. 4, Dresden, 01062, Germany, (3) Nanostructured Materials, Leibniz Institut für Polymerforschung Dresden e.V, Hohe strasse 6, Dresden, 01069, Germany
In this paper, preparation and characterisation of Polystyrene-ZnO hybrid nanoparticles are reported. These composite nanoparticles are prepared by two steps method in which first step consists of preparation of the functionalised core polystyrene particles and second step is the deposition of ZnO nanoparticles on the surface of prepared polystyrene core particles. The procedure gives possibility to obtain composite particles with core-shell morphology, where both core size and ZnO shell thickness can be varied by changing the reaction parameters. Effect of NaOH concentration and polymeric core size, on the thickness of inorganic shell and morphology of resulting hybrid nanoparticles is investigated. Morphology of polymeric composite particles is characterised by SEM and ZnO content is determined by TGA. Presence of ZnO nanoparticles on the surface of hybrid nanoparticles is confirmed by XPS.
 

Nanoparticles and Microparticles: Synthesis and Applications
6:00 PM-8:00 PM, Tuesday, 12 September 2006 Moscone Center -- Hall D, Poster

Sci-Mix
8:00 PM-10:00 PM, Monday, 11 September 2006 Moscone Center -- Hall D, Sci-Mix

Division of Polymer Chemistry

The 232nd ACS National Meeting, San Francisco, CA, September 10-14, 2006