Determining the occurrence toxicity, and composition of mixtures of urban-use insecticides

AGRO 162

Andrew J. Trimble and Michael J. Lydy. Fisheries and Illinois Aquaculture Center, Department of Zoology, Southern Illinois University Carbondale, 1125 Lincoln Drive, Life Science II Room 173, Mailcode 6511, Carbondale, IL 62901
Over the last sixty years, insecticides from a number of different chemical classes have been used in both agricultural and urban settings. Organochlorine (OC), organophosphate (OP) and, more recently, pyrethroid insecticides have dominated the commercial market and have been detected together in sediment samples. The large number of chemicals often present together can confound attempts to determine the hazard posed by individual components of the mixture. The objective of this study was to analyze a pre-constructed database of chemical concentrations in sediment samples collected from streambeds receiving runoff from urban environments throughout California's Central Valley. Samples were analyzed for 28 different insecticides. A censoring approach was used to eliminate negligible compounds in order to identify mixture components that dominated sample toxicity to Hyalella azteca. Seven pyrethroids and chlorpyrifos were found to account for nearly all of the toxicity in a majority of samples with tertiary mixtures of pyrethroids dominating the toxicity in most cases.
 

Synthetic Pyrethroids and Surface Water Quality Poster Session
1:00 PM-5:00 PM, Tuesday, 12 September 2006 Moscone Center -- Hall D, Poster

Sci-Mix
8:00 PM-10:00 PM, Monday, 11 September 2006 Moscone Center -- Hall D, Sci-Mix

Division of Agrochemicals

The 232nd ACS National Meeting, San Francisco, CA, September 10-14, 2006