AFM analysis of C60 and a PAMAM dendrimer-C60 nanoconjugate

POLY 116

Minghui Chai, minghui.chai@cmich.edu1, Anton W. Jensen, anton.w.jensen@cmich.edu1, Hosam G. Abdelhady, abdel1hg@cmich.edu1, and Donald Tomalia2. (1) Department of Chemistry, Central Michigan University, Mt. Pleasant, MI 48859, (2) Dendritic Nanotech Ltd, 2625 Denison Dr Ste B, Mount Pleasant, MI 48858-5596
Atomic force microscopy (AFM) was used to study the nanoscopic structure and topography of buckminsterfullerene (C60) and a conjugate of C60 with generation four, amine-terminated, poly(amido amine) dendrimer (PAMAM-G4). The conjugate contains a PAMAM-G4 core and C60 shell formed by reacting PAMAM-G4 with an excess of C60. Fractal patterns of C60 were observed in nanoscopic AFM images when solutions of different concentrations of C60 in pyridine or toluene were dried at room temperature. In contrast, no fractal patterns were detected in the AFM images of the dendrimer-C60 nanoconjugate, prepared from pyridine solution in a similar manner. Thus, the C60-shell alone is not sufficient to impart the same fractal patterns on the conjugate.
 

General Papers: Polymers in Nanotechnology
6:00 PM-8:00 PM, Sunday, 10 September 2006 Moscone Center -- Hall D, Poster

Sci-Mix
8:00 PM-10:00 PM, Monday, 11 September 2006 Moscone Center -- Hall D, Sci-Mix

Division of Polymer Chemistry

The 232nd ACS National Meeting, San Francisco, CA, September 10-14, 2006