Superparamagnetic iron oxide - containing polydiacetylenic liposomes

POLY 235

Yu Cai, yu.cai@dartmouth.edu1, Ebo D. de Muinck2, and Robert B. Grubbs, Robert.B.Grubbs@Dartmouth.EDU1. (1) Department of Chemistry, Dartmouth College, 6128 Burke Laboratory, Hanover, NH 03755, (2) Angiogenesis Center, Section of Cardiology, Dartmouth Medical School, Lebanon, NH 03756
Diacetylene-functional DTPA-TEG-PDA lipids and their biotin derivatives were prepared and used to prepare cross-linkable liposomes. Dextran-coated superparamagnetic iron oxide (SPIO) nanoparticles have been made and they are small enough that they can be encapsulated into the DTPA-TEG-PDA liposomes. The resulting nanoparticle-containing liposomes can then be photo-crosslinked via their diacetylenic moieties. In the case that biotin groups are on the surfaces of liposomes, these nanoparticles can be linked to targeting moieties, such as oligopeptides containing Asn-Gly-Arg (NGR) sequences, by means of a biotin-avidin “bridge”. The targeting groups may thus direct the nanoparticles towards neovasculature by NGR-CD13 recognition.