Measurement of carbon nanotube dispersion by size exclusion chromatography

POLY 515

Barry J. Bauer, barry.bauer@nist.gov1, Vardhan Bajpai, vardhan.bajpai@nist.gov2, Matthew L. Becker, matthew.becker@nist.gov1, Jeffrey Fagan, jeffrey.fagan@nist.gov1, Erik K. Hobbie, erik.hobbie@nist.gov1, and Kalman B. Migler, kalman.migler@nist.gov1. (1) Polymers Division, National Institute of Standards and Technology, 100 Bureau Drive, stop 8541, Gaithersburg, MD 20899-8541, (2) Polymers Division, NIST, 100 Bureau Drive, stop 8541, Gaithersburg, MD 20899-8541
Size exclusion chromatography (SEC) is shown to be an effective method to characterize single wall carbon nanotube (SWNT) dispersions. SEC separates nanotube dispersions by size, and measures the intrinsic viscosity on-line as a function of hydrodynamic size as is determined by Universal Calibration. This scaling contains information about the shape of the dispersed particles. This characterization method was tested on three representative dispersions: octadecyl amine functionalization in tetrahydrofuran (THF), butyl group functionalization in THF, and DNA wrapping in aqueous solution. Significant differences between the dispersions were found. Small angle neutron scattering (SANS) and atomic force microscopy (AFM) produced results consistent with the SEC method.
 

Nanoparticles and Microparticles: Synthesis and Applications
6:00 PM-8:00 PM, Tuesday, 12 September 2006 Moscone Center -- Hall D, Poster

Division of Polymer Chemistry

The 232nd ACS National Meeting, San Francisco, CA, September 10-14, 2006