Biological assaying in the near-field and with microelectronic biochips

ANYL 411

Rastislav Levicky, RL268@columbia.edu1, Barry Friedman2, Maria Francis A Gaspar1, Kiejin Lee3, George Patounakis4, Kenneth Shepard4, and Gang Shen, gs617@columbia.edu1. (1) Department of Chemical Engineering, Columbia University, RM 801 Mudd BLDG, 500 W. 120th ST. MC4721, New York, NY 10027, (2) Department of Physics, Sam Houston State University, Huntsville, TX 77340, (3) Department of Physics, Sogang University, Seoul, South Korea, (4) Department of Electrical Engineering, Columbia University, New York, NY 10027
Detection of biological analytes in complex sample environments is often implemented at a solid-liquid interface. This talk will describe principles for label-free analysis being established using near-field optical methods in the GHz regime. Sensitivities comparable to fluorescence-based assay using conventional instrumentation, but without the need for any kind of analyte labeling, have been demonstrated. In parallel, we are developing microelectronic chips that serve as functional solid supports with integrated circuitry for control and detection of binding between surface-immobilized and free (analyte) species. By integration of the respective functions on-chip, these devices can replace macroscopic instrumentation at minimal cost by drawing on affordable CMOS manufacture. The design and validation of several prototypes for fluorescence-based measurements will be described, including designs with conventional optical filter-based approach as well as ones based on a time-resolved fluorescence (TFR) technique. Results from validation studies of these emerging technologies and their promise for more portable, simplified, and economical assays will be described.