Cationic cyclodextrin nanosphere/anionic polymers as novel flocculation/sorption systems

COLL 279

Huining Xiao and Norlito Cezar. Department of Chemical Engineering, University of New Brunswick, 15 Dineed Dr, Fredericton, NB E3B 5A3, Canada
Simultaneous removal of dissolved and colloidal substances (DCS) or contaminants for water clarification has been a challenging task due to the different characteristics of each component. In this work, a range of cationic cyclodextrins (C-CD) was synthesized in order to provide a novel approach for the problems addressed. C-CDs as functional nanospheres, in conjunction with water-soluble anionic polymers, consisted of an excellent dual-component flocculation system for fine colloidal particles (e.g., fine clay). Meanwhile, C-CD nanospheres as absorbents effectively removed dissolved or soluble substances via inclusion complex formation, facilitating the simultaneous removal of DCS. To optimize the flocculation/sorption systems, a number of factors, such as C-CD/polymer dosages, charge density of anionic polymers, pH and electrolyte concentration, were systematically investigated. Interactions between C-CD and colloidal particles as well as C-CD and dissolved aromatic compounds were also explored in attempt to elucidate the flocculation/sorption mechanisms involved in the current systems.