COLL 343 |
| C. M. Friend, Dae-hyuk Kang, Juergen Biener, Monika Biener, Xingyi Deng, and Dilini Pinniduwage. Department of Chemistry & Division of Engineering & Applied Sciences, Harvard University, 12 Oxford Street, Cambridge, MA 02138 |
| The transfer of alkyl groups to oxygen on Mo oxide surfaces will be reported. The alkyl transfer processes were investigated using a combination of vibrational spectroscopy (high resolution electron energy loss and infrared absorption reflection spectroscopies) in conjunction with scanning tunneling microscopy. Vibrational spectroscopy also played an important role in characterizing the MoO3 nanostructures, showing the presence of both bridge bonded and terminal oxygen species. Reactions to be described include those of organic thiols (RSH) and alcohols. We specifically address the role of oxidation state and structure in this work. |
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Vibrational Analyses of Dry and Wet Surfaces
2:00 PM-5:30 PM, Tuesday, March 30, 2004 Marriott -- Grand Ballroom H, Oral
Division of Colloid and Surface Chemistry |