IEC 168 |
| W. Matthew Reichert1, John D. Holbrey1, M. Nieuwenhuyzen2, O Sheppard2, C. Hardacre2, and Robin D. Rogers1. (1) Department of Chemistry and Center for Green Manufacturing, The University of Alabama, Tuscaloosa, AL 35487, (2) School of Chemistry, The Queen's University of Belfast, David Keir Building, Stranmillis Road, BT9 5AG Belfast, United Kingdom |
| Evidence that liquid clathrate formation is a general phenomena in mixtures of ionic liquids with aromatic hydrocarbons is given: ionic liquids containing 1-alkyl-3-methylimidazolium cations and hexafluorophosphate, bis (trifyl) imide, tetrafluoroborate, and chloride anions form liquid clathrates when mixed with aromatic hydrocarbons. In the system 1,3-dimethylimidazolim hexafluorophosphate/benzene, the aromatic solute could be trapped in the solid state forming a crystalline 2:1 inclusion compound. |
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General Poster Session
5:00 PM-7:00 PM, Tuesday, March 25, 2003 Convention Center -- Hall G, Poster
Sci-Mix
Division of Industrial and Engineering Chemistry |